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A systematic study on the use of short circuiting for the improvement of proton exchange membrane fuel cell performance

机译:关于使用短路改善质子交换膜燃料电池性能的系统研究

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摘要

Proton exchange membrane fuel cells suffer from reversible performance loss during operation caused by the oxidation of the Pt catalyst which in turn reduces the electrochemically active surface area. Many fuel cell manufacturers recommend using short circuiting during the operation of the fuel cell to improve the performance of the cells over time. However, there is lack of understanding on how it improves the performance as well as on how to optimise the short circuiting strategy for different fuel cell systems. We present a simple procedure to develop an optimised short circuiting strategy by maximising the cumulative average power density gain and minimising the time required to recover the energy loss during short circuiting. We obtained average voltage improvement from 10 to 12% at different current densities for a commercial H-100 system and our short circuiting strategy showed ~2% voltage improvement in comparison to a commercial strategy. We also demonstrated that the minimum short circuiting time is a function of double layer capacitance by the use of electrochemical impedance spectroscopy.
机译:质子交换膜燃料电池在操作过程中会因Pt催化剂的氧化而导致可逆的性能损失,进而降低电化学活性表面积。许多燃料电池制造商建议在燃料电池运行期间使用短路功能,以改善电池的性能。但是,对于如何提高性能以及如何针对不同的燃料电池系统优化短路策略,尚缺乏了解。我们提出了一个简单的程序,通过最大化累积平均功率密度增益并最小化恢复短路期间的能量损耗所需的时间来开发优化的短路策略。对于商用H-100系统,在不同的电流密度下,我们将平均电压提高了10%至12%,与商业策略相比,我们的短路策略显示电压提高了约2%。通过使用电化学阻抗谱,我们还证明了最小短路时间是双层电容的函数。

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